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Search Results for Collection: Chemistry and Chemical Biology Research Collection
Now showing items 1-6 of 6
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(Elsevier, 2012-01)N-heterocyclic carbene (NHC) coordination to a cobalt(III) center embedded in a porphyrin scaffold has been accomplished by decarboxylation from N,N’-dimethylimidazolium-2-carboxylate in the presence of Co(TPP)Cl (TPP = ...
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(Wiley-VCH, 2012-03)Oxidative addition of donor-functionalised 4-iodoimidazolium salts to palladium(0) provides a selective route for the preparation of chelating abnormal N-heterocylic carbene complexes and enables the introduction of a ...
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(Wiley-VCH, 2012-01-09)Rhodium(III) complexes comprising monoanionic C,C,C-tridentate dicarbene ligands activate Si–H bonds and catalyse the hydrolysis of hydrosilanes to form silanols and siloxanes with concomitant release of H2. In dry MeNO2, ...
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(Wiley, 2012-01-16)The development of novel chiral amphiphilic self-assembled complexes 13Eu and 23Eu by using Europium(III) directed synthesis is described. These systems form stable Langmuir films at an air-water interface, which were ...
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(ACS, 2012-01-13)A series of palladium complexes were synthesized that comprise three sterically different C,N-bidentate coordinating NHC-pyridine ligands (NHC = N-heterocyclic carbene). In one set, the pyridine and the carbene are linked ...
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A magnetic iron(III) switch with controlled and adjustable thermal response for solution processing (RSC, 2012-02-27)Spin crossover requires cooperative behaviour of the metal centers in order to become useful for devices. While cooperativity is barely predictable in solids, we show here that solution processing and the covalent introduction ...
Now showing items 1-6 of 6