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Browsing Chemistry and Chemical Biology Research Collection by Title
Now showing items 22-41 of 65
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(Springer Science+Business Media, 2012-11)The EE subunit of horse liver alcohol dehydrogenase (HLADH-EE) has been subcloned in pRSETb vector to generate a fusion His-tag protein. The migration from a multistep purification protocol for this well-known enzyme to ...
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(RSC Publishing, 2012)Carbon based materials are attractive for biological applications because of their excellent biocompatibility profile. Porous carbons with high specific surface area are particularly interesting because it is possible in ...
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(Elsevier, 2005-07)Na/Al2O3 catalysts are tested in the soot oxidation reaction using O-2 and NO/O-2 as oxidising agents. The activity of the catalysts . varies with oxidising agent and the presence of surface SO42-.. NO(g) increases conversion ...
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(Springer, 2011)The wastewater generated at a facility specialising in potato processing was found to contain high levels of insoluble potato starch. Several separation methods were employed to obtain maximum potato starch recovery from ...
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A magnetic iron(III) switch with controlled and adjustable thermal response for solution processing (RSC, 2012-02-27)Spin crossover requires cooperative behaviour of the metal centers in order to become useful for devices. While cooperativity is barely predictable in solids, we show here that solution processing and the covalent introduction ...
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(RSC, 2009)Main-chain organometallic polymers were synthesized from bimetallic iron(II)complexes containing a ditopic N-heterocyclic carbene (NHC) ligand [(cp)(CO)LFe(NHC~NHC)Fe (cp)(CO)L]X2 (where NHC~NHC represents a bridging ...
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(Springer, 2013-04)Two Al2O3-supported alkaline earth metal oxide catalysts (MgO and BaO) were contacted with valeric acid at 250 °C. Each formed amounts of 5-nonanone (BaO more than MgO). A significant deposition of hydrocarbonaceous material ...
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(Elsevier, 2010-10-13)The use of I2/AgOAc in dichloromethane constitutes a cheap, mild, and efficient method for the selective iodination of a variety of heterocycles. In a number of cases, this method provides superior yields than other ...
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(Elsevier, 2005-02-10)The temperature-programmed activity of a series of oxide-supported (TiO2, Al2O3 and SiO2) Cu catalysts formed from two different Cu precursors (Cu(NO3)(2) and CuSO4) for the selective catalytic reduction of NOx using ...
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(Elsevier, 2012-01)N-heterocyclic carbene (NHC) coordination to a cobalt(III) center embedded in a porphyrin scaffold has been accomplished by decarboxylation from N,N’-dimethylimidazolium-2-carboxylate in the presence of Co(TPP)Cl (TPP = ...
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(RSC Publishing, 2010)The expansion of the concept of N-heterocyclic carbenes as ligands for transition metals to mesoionic ligand systems has led to the discovery of a wide range of non-classical carbene-type ligands. These non-classical ...
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(Elsevier, 2012-09)A new practical and efficient synthesis of alpha-keto acids was accomplished starting from the synthon 1,4-diacetylpiperazine-2,5-dione. The synthesis encompasses both aromatic and aliphatic substrates proving to be versatile ...
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(Elsevier, 2009-04-15)A simple and efficient one-step procedure is described for the synthesis of a number of symmetrical 1,4-disubstituted piperazine-2,5-diones under phase transfer conditions. The reactions are carried out at room temperature, ...
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(RSC Publishing, 2010)New sal2(trien) ligands that contain alkoxy substituents of various length in meta position of the salicyl entities were coordinated to electronically and magnetically active iron(III) and cobalt(III) centers. The ...
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(ACS, 2012-01-13)A series of palladium complexes were synthesized that comprise three sterically different C,N-bidentate coordinating NHC-pyridine ligands (NHC = N-heterocyclic carbene). In one set, the pyridine and the carbene are linked ...
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(RSC Publishing, 2012-09-24)The photophysical properties of 2.3 nm thioglycolic acid (TGA) coated CdTe quantum dots (QDs) prepared by a reflux method have been studied in the presence of cationic meso-tetrakis(4-N-methylpyridyl) zinc porphyrin ...
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The Potential of N-Heterocyclic Carbene Complexes as Components for Electronically Active Materials (Swiss Chemical Society, 2010-03)The application of N-heterocyclic carbene complexes as active sites in materials other than catalysis has been remarkably scarce. Inspired by the — often misleading — ‘carbene’ label, which implies a substantial degree of ...
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(American Chemical Society, 2007-12-04)4-Dimethylaminopyridine (DMAP)-stabilized palladium nanoparticles with a mean diameter of 3.4 +/- 0.5 mn are prepared from the aqueous phase reduction of Na2PdCl4 using NaBH4 in the presence of DMAP. TEM and UV-vis ...
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(Springer, 2013-03)The preparation of supported and unsupported group II oxide catalysts through oxidation of analogous group II acetates (Mg, Ca and Ba) in the presence and absence of a mesoporous silica material (SBA-15) was analysed using ...
Now showing items 22-41 of 65