New sal2(trien) ligands that contain alkoxy substituents of various length in meta position of the salicyl entities were coordinated to electronically and magnetically active iron(III) and cobalt(III) centers. The ...
Abnormal isoxazolylidene complexes, a new subclass of mesoionic complexes containing an isoxazolium-derived carbene type ligand, have been synthesised via oxidative addition and compared to structurally related mesoionic ...
This tutorial review compiles the advances that have been achieved in using transition metal complexes containing N-heterocyclic carbene ligands as components for materials. Applications of metal carbene complexes in fields ...
An efficient one-pot synthesis is described for the preparation of 1,4-disubstituted piperazine-2,5-diones
starting from a suitable amine and chloroacetyl chloride in the presence of an aqueous base. The resulting
chlo ...
An atom-efficient and stereoselective synthesis has been developed for the preparation of a-2H-labelled(S)-a-amino acids, starting from a novel chiral diketopiperazine scaffold. Efficient mono-alkylation of the chiral ...
We report a thorough investigation of a series of isomeric complexes with the general formula trans-(pyridylidene)M(PPh3)2Cl (M = Pd, Ni). For the first time, a systematic comparison of normal, abnormal and remote bonding ...
Pt/BaO/Al2O3 catalysts react with NO/O2 mixtures to form barium nitrites and nitrates. In the presence of small amounts of C(s) admixed with the catalyst the concentrations of NOx adsorbed is considerably reduced and the ...
Using microwave irradiation, water soluble, optically active, penicillamine (Pen) capped CdSe nanocrystals with broad spectral distribution (430-780 nm) of photoluminescence have
been produced and studied by a range of ...
The photophysics and photochemistry of [Cr(phen)2(dppz)]3+ and its 11,12-substituted derivatives [Cr(phen)2(X2dppz)]3+
{X = Me or F} have been studied in the presence of purine nucleotides
or DNA using steady state and ...