This tutorial review compiles the advances that have been achieved in using transition metal complexes containing N-heterocyclic carbene ligands as components for materials. Applications of metal carbene complexes in fields ...
Abnormal isoxazolylidene complexes, a new subclass of mesoionic complexes containing an isoxazolium-derived carbene type ligand, have been synthesised via oxidative addition and compared to structurally related mesoionic ...
Rhodium(III) complexes comprising monoanionic C,C,C-tridentate dicarbene ligands activate Si–H bonds and catalyse the hydrolysis of hydrosilanes to form silanols and siloxanes with concomitant release of H2. In dry MeNO2, ...
The use of I2/AgOAc in dichloromethane constitutes a cheap, mild, and efficient method for the selective iodination of a variety of heterocycles. In a number of cases, this method provides superior yields than other ...
It is known that, for any simply connected proper subdomain Ω of the complex plane and any point ζ in Ω, there are holomorphic functions on Ω that possess “universal” Taylor series expansions about ζ; that is, partial sums ...
The application of N-heterocyclic carbene complexes as active sites in materials other than catalysis has been remarkably scarce. Inspired by the — often misleading — ‘carbene’ label, which implies a substantial degree of ...
Two bimetallic cryptates (containing Cu and Co), which have previously been shown to react with and activate atmospheric CO2, have been tethered to modified mesoporous SiO2 and their activities in promoting the CO2 + H2 ...
We survey some work concerned with small universal Turing machines, cellular automata, tag systems, and other simple models of computation. For example it has been an open question for some time as to whether the smallest ...