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Rhodium-mediated activation of an alkane-type C–H bond

Krüger, Anneke ; Neels, Antonia ; Albrecht, Martin (RSC Publishing, 2010-01-14)

Abnormal C4-bonding of N-heterocyclic carbenes effectively modulates the electron density at rhodium and allows for the selective cleavage of an unactivated C(sp3)–H bond, whereas no such intramolecular C–H bond breaking ...
Rhodium carbene complexes as versatile catalyst precursors for Si–H bond activation

Krüger, Anneke ; Albrecht, Martin (Wiley-VCH, 2012-01-09)

Rhodium(III) complexes comprising monoanionic C,C,C-tridentate dicarbene ligands activate Si–H bonds and catalyse the hydrolysis of hydrosilanes to form silanols and siloxanes with concomitant release of H2. In dry MeNO2, ...

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